Organic luminous diode, method for the production thefeof and uses thereof

ABSTRACT

The invention relates to an organic light emitting diode (OLED), also referred to as a light emitting diode, which comprises at least one substrate, one anode, one perforated transport layer, one emitter layer, one cathode and one encapsulation. It is proposed that an energy carrier, which supplies the voltage that causes the OLED to emit light, be integrated into the OLED. The energy carrier can be a battery (energy storage device) or an energy converter (photovoltaic element).

The invention relates to an organic light emitting diode (OLED), also referred to as a light emitting diode, which comprises at least one substrate, one anode, one emitter layer and one cathode, and has a new type of energy supply.

Light emitting diodes are known that show luminescence with simultaneous current flow as a result of the application of voltage. A disadvantage of the OLEDs known to date is that they derive their energy exclusively from an external electrical power supply.

The goal of the invention is to create an OLED with an integrated energy carrier, so that the OLED can be operated in mobile manner, i.e., at least partly independent of a power source.

The subject matter of the invention is an organic light emitting diode (OLED), comprising at least one substrate, one anode, one emitter layer and one cathode, wherein an energy carrier is integrated into the OLED, so that a voltage can be applied to the OLED, either through switching and/or through environmental influence. A production process for producing an OLED with an integrated energy carrier is also a subject matter of the invention and, finally, a subject matter of the invention is the use of such OLEDs in displays and/or in electronic paper, as described, for example, in “Rubber Stamping for Plastic Electronics and fiber Optics” by John A. Rogers, in MRS (Materials Research Society) Bulletin, July 2001, pages 530 to 532.

An energy storage device, such as a conventional or rechargeable battery and/or an energy converter,

such as a photovoltaic cell or solar cell, can be used as an energy carrier.

Radiation (especially light radiation in the visible spectrum, such as that generated by common lighting fixtures or by sunshine), heat, pressure or a source of sound can be used as an environmental influence.

According to one embodiment of the OLED, the energy carrier, such as the photovoltaic cell, acts in such a way that it is simultaneously a photodetector that detects, for example, when the mobile telephone is removed from a pocket and/or the cover of the mobile telephone is opened. In this manner, a network operator of the mobile telephone, which uses a relatively large amount of current, can only be activated in suitable ambient light. When the mobile telephone is in the light but not in operation, the solar cell supplies the energy and the signal to activate the network operator on the display as needed.

The energy carrier, which must at least also serve as an energy storage device, can be switched on and off by means of a circuit.

Because only small amounts of energy are necessary to operate an OLED, the electric power can be generated, in part or in full, through photovoltaic cells as energy converters. In this process, semitransparent photovoltaic elements are recommended, which can be disposed on the transparent side of the OLED and, specifically, in such a way that, for example, the entire surface of the OLED is made usable for energy conversion.

Semitransparent photovoltaic elements preferably have a photovoltaic layer which is not silicon-based but is constructed on the basis of organic material.

A suitable photovoltaic layer is known from U.S. Pat. No. 5,454,880 and U.S. Pat. No. 5,333,183, among others, and can comprise one or more semiconducting plastics that can exist in monomer, oligomer and/or polymer form, as well as inorganic particles and/or nanoparticles. A mixture of two or more conjugated organic plastics, inorganic particles and/or nanoparticles with similar or different electron affinities and/or with similar or different band gaps can be present.

Thin layers of organic molecules, oligomers and molecular mixtures can be produced by thermal vapor deposition or chemical/physical vapor deposition (CVD), for example.

Thin layers of conjugated polymers and mixtures with conjugated polymers can be produced by spin-coating (solution spinning), but also by other common printing methods, such as silk screen printing, ink jet printing, flexographic printing or rotogravure (or other/similar solvent deposition processes). If polymers are used, these layers can also be deposited onto flexible substrates.

Examples of typical semiconducting conjugated polymers include polyacetylene (PA) and derivatives thereof, polyisothianaphtene (PITN) and derivatives thereof, polythiophene (PT) and derivatives thereof, polypyrroles (PPr) and derivatives thereof, poly(2,5-theinylenevinylene) (PTV) and derivatives thereof, polyfluorene (PF) and derivatives thereof, poly(p-phenylene) (PPP) and derivatives thereof, poly(phenylene vinylene) (PPV) and derivatives thereof, as well as polyquinoline and derivatives thereof, polycarbazol and derivatives thereof, and semiconducting polyaniline (leukoemeraldine and/or leukoemeraldine base).

Examples of acceptors in donor/acceptor polymer mixtures include, but are not limited to poly-(cyanophenylenevinylene), fullerene such as C60 and its functional derivatives (such as PCBM, PCBR), and organic molecules, organometallic molecules or inorganic nanoparticles (such as CdTe, CdSe, CdS, CIS).

Solar cells that are used can also be constructed in two separate layers, in which the donor is spatially separated from the acceptor (such as PT/C60 or PPV/C60).

According to a preferred embodiment of the invention, the OLED has a layer of semitransparent photovoltaic elements, wherein one of the electrodes of the OLED also serves as an electrode for the photovoltaic element. Not only does this reduce production costs, because the production of an electrode layer for the photovoltaic element is eliminated, but the material and spatial requirements for the energy converter are also reduced.

According to a preferred embodiment, the energy carrier is transparent or at least semitransparent. If the energy converter comprises cells and/or is transparent or semitransparent, it is recommended that the energy converter be disposed within the OLED in such a way that the energy converter is mounted on the side of the OLED facing the light source, so that there is no obstruction of the radiation falling onto the photovoltaic cells.

Transparent ITO (indium tin oxide) or gold (Au), for example, are used as the anode for an OLED.

Preferably, the OLED also has a perforated transport layer. A layer of conductive, semitransparent PANI and/or PEDOT/PSS, for example, is used for this purpose.

PPV and/or PF as well as their derivatives, for example, are used as an emitter layer and/or electron guiding layer.

Ca, Sm, Y, Mg, Ak, In, Cu, Ag, Au, LiF/Al, LiF/Ca, for example, are used as a cathode.

Preferably, the OLED is also encapsulated. A glass layer, for example, that is glued, laminated, etc. to the OLED (solar cell) may be used for this purpose.

According to a preferred embodiment, there is at least one semitransparent insulation layer between the OLED and the solar cell. In addition to encapsulation and electrical insulation, this layer can also have other functions, such as oxygen and/or water stabilizers, polarizers for OLEDs color filter, anti-reflection layer for OLED and/or solar cells, refractive index matcher, etc.

Because it is often difficult to obtain pure colors with the OLED displays, the solar cells can also be used as color filters to filter the interfering portion out of the overall OLED emission.

In the following, the invention is explained on the basis of a few figures, which show the preferred embodiments with at least one photovoltaic element as an energy converter.

FIGS. 1 to 6 show the combination of an OLED with a semitransparent solar cell.

In FIG. 1, one can see the combination of an OLED 1 with a semitransparent solar cell 2, in which both the solar cell 2 and the OLED 1 are produced separately. From bottom to top, one can see the substrate 3 (such as glass or a flexible film) with a spacer 4. The incident light (arrows 9) and, in reverse direction, the emission of the OLED, indicated by the arrows 10, penetrate through this substrate. Disposed on this substrate 3 are the positive electrode, the anode 8, which can be made of ITO (indium tin oxide), for example, on the anode 8 the semitransparent photoactive layer 7 of the solar cell 2 (the absorber), and the cathode 5, which can be made of calcium (Ca), for example. The solar cell 2 is sealed by the semitransparent insulation layer 11. Spacers 4 protect the cathode 5 against damage. The semitransparent insulation layer 11 serves as a substrate for the OLED 1. The OLED 1 is constructed on it: What can be seen, again from bottom to top, is first the anode 8, then the photoactive layer of the OLED 6 (the emitter), on top of it the cathode 5 and, finally, the encapsulation or seal 12, which is comprised of glass, for example.

The OLED 1 can then be sealed, for example, and the semitransparent insulation layer 11 (or the substrate 11) of the OLED 1 serves, in turn, as a seal for the solar cell 2.

FIG. 2 is largely the same as FIG. 1. What can be seen is the combination of an OLED 1 with a semitransparent solar cell 2, in which both the solar cell 2 and the OLED 1 are produced on the same substrate, the semitransparent insulation layer 11, which, in this case, is coated on both sides. The OLED 1 and the solar cell 2 can then be sealed separately. In this connection, the anodes 8 of the components OLED 1 and solar cell 2 are adjacent to the two sides of the semitransparent insulation layer 11, followed by their respective photoactive layers 6 and 7 and, finally, their cathodes 5.

FIG. 3 shows a structure in which the OLED 1 is applied in a self-supporting manner, through a connecting electrode or conductive electrode 13, to the upper sealing layer 12, which can be made of glass, for example. The OLED 1 is applied to the conductive electrode 13, which can be an aluminum adhesive strip, carbon black or another form of intermediate layer,

by means of printing, gluing, etc. The connecting or conductive electrode 13 is followed by the cathode 5, the photoactive layer 6 and the semitransparent insulation layer 11, which is a thin substrate that can also be flexible. The insulation layer 11 can also be referred to here as a planarization layer.

The self-supporting OLED 1 is separated from the lower semitransparent solar cell 2 by the spacers 4. The structure of the semitransparent solar cell 2 corresponds to that shown in FIG. 1.

Shown here is the combination of an OLED 1 with a semitransparent solar cell 2, in which the solar cell 2 is produced separately. Either the OLED 1 can be produced from an optional independent substrate 12, sealed, and then connected to the connecting electrode 13, which is also a conductive electrode, or the two individual elements are sealed together by the spacers 4.

The example shown in FIG. 4 is again similar, in terms of its principle parts, to the structure from FIG. 1, in which the OLED 1 is shown in the center as a substrate and the encapsulation of the solar cell 2 as a thin substrate, which can be optionally provided with a getter function. This is the combination of an OLED 1 with a semitransparent solar cell 2, in which the solar cell 2 is produced separately. The OLED 1 is, for example, structured in reverse order. The two individual elements are sealed together.

Elements known from FIGS. 3 and 4 are connected in FIG. 5. Here, as an option, the individual elements OLED 1 and solar cell 2 can be designed to be monolithic relative to one another. First, the solar cell 2 is produced on the substrate 3, which is coated with the anode 8, and is then sealed with a semitransparent insulation layer 11, which can be an optional planarization layer and/or a thin substrate, which can also be flexible and/or be provided with a getter function. The OLED 1 is built onto this layer 11. Finally, the entire structure, which comprises the OLED 1 and the solar cell 2, is sealed by means of a suitable connecting electrode 13. It is also conceivable that the semitransparent insulation layer 11 be omitted and the OLED 1 be built onto the anode 8 of the solar cell 2. The OLED 1 and the solar cell 2 utilize the same electrodes. This embodiment is especially characterized by its compactness.

The semitransparent insulation layer 11 also makes it possible to produce the two cells individually and then glue them together using this layer.

FIG. 6 shows an embodiment which, with the exception of the placement of the connecting electrode 13, is identical to that shown in FIG. 5. Here the connecting electrode 13 is disposed between the solar cell 2 and the substrate 3, through which the emission of the OLED 10 and the radiation 9 for the solar cell 2 passes.

This, therefore, is a combination of an OLED 1 and a semitransparent solar cell 2, in which the individual elements are designed to be monolithic relative to one another (see FIG. 5). In this case, however, construction occurs in the reverse order. The OLED 1 is first produced on a suitable substrate, and is then passivated or sealed with a semitransparent insulation layer 11 (optional), wherein the solar cell 2 is constructed on the optional insulation layer 11 or on the anode 8 of the OLED 1. Finally, the entire component is sealed by means of a suitable connecting electrode 13.

The optional insulation layer 11 also makes it possible to produce the OLED 1 and the solar cell 2 individually, and then glue them together using the insulation layer 11.

Again, it is conceivable that the semitransparent insulation layer 11 be omitted and the OLED 1 be built onto the anode 8 of the solar cell 2. Again, the OLED 1 and the solar cell 2 would utilize the same anode 8.

The functioning OLED can also comprise several modules, therefore, in most cases, control electronics will be indispensable. Likewise, several solar cells are presumably connected in series to supply the necessary operating voltage, although the solar cell(s) can also contribute to the operation voltage in combination with other energy carriers.

In general, the semitransparent insulation layer 11 in these structures can have a wide variety of functions. It can comprise an oxygen and/or water stabilizer, polarizer(s) for OLEDs, possibly color filters, anti-reflection layers for OLEDs or solar cells and/or refractive index matchers for solar cells and/or OLEDs, etc.

Although the figures only describe solar cells as energy carriers, by no means should the invention be limited to this type of energy carrier. Instead, energy storage devices such as rechargeable batteries can certainly also be described as preferred embodiments.

Likewise, the cathode/anode assignment in the examples is also simply coincidental and should not restrict the scope of the invention to be protected here. To a person skilled in the art, it is obvious that an operative device can also be obtained with a different choice of electrodes.

Similarly, the light source/semitransparent solar cells/OLED arrangement depicted here should not be restrictive. Instead, it is certainly also an aspect of the invention that the OLED can be produced to be semitransparent and that the energy carrier is not transparent and is disposed behind the OLED.

The invention relates to an organic light emitting diode (OLED), also referred to as a light emitting diode, which comprises at least one substrate, one anode, one perforated transport layer, one emitter layer, one cathode, and one encapsulation. It is proposed that an energy carrier, which supplies the voltage that causes the OLED to emit light, be integrated into the OLED. The energy carrier can be a battery (energy storage device) or an energy converter (photovoltaic element). 

1-12. (canceled)
 13. A light emitting device, comprising: one or more substrates; an organic light emitting diode supported by the one or more substrates, wherein the organic light emitting diode comprises: a first electrode; an emitter layer disposed on the first electrode; and a second electrode disposed on the emitter layer; and an energy source to apply a voltage to the organic light emitting diode, wherein the energy source is supported by the one or more substrates.
 14. The device according to claim 13, further comprising: an encapsulation that encapsulates the energy source.
 15. The device according to claim 14, wherein: the encapsulation includes a sealing layer.
 16. The device according to claim 13, further comprising: an encapsulation that encapsulates the organic light emitting diode.
 17. The device according to claim 16, wherein: the encapsulation includes a sealing layer.
 18. The device according to claim 13, wherein: the energy source is an energy converter.
 19. The device according to claim 18, wherein: the energy converter comprises a photovoltaic element.
 20. The device according to claims 18, wherein: the one or more substrates includes a semitransparent insulation layer and the semitransparent insulation layer is between the organic light emitting diode and the energy converter.
 21. The device according to claims 20, wherein: the semitransparent insulation layer comprises at least one of a planarizing layer, a thin substrate, a flexible layer and a getter layer.
 22. The device according to claim 13, wherein: the energy source is an energy storage device.
 23. The device according to claim 22, wherein: the one or more substrates include a semitransparent insulation layer and the semitransparent insulation layer is between the organic light emitting diode and the energy storage device.
 24. The device according to claim 23, wherein: the semitransparent insulation layer comprises at least one of a planarizing layer, a thin substrate, a flexible layer and a getter layer.
 25. The device according to claim 13, wherein: the energy source is at least semitransparent.
 26. The device according to claim 13, wherein: the organic light emitting diode is supported by a first substrate of the one or more substrates; the energy source is supported by a second substrate of the one or more substrates; and the first and second substrates encapsulate the organic light emitting diode and the energy source.
 27. The device according to claim 13, wherein: the organic light emitting diode is supported by a first side of a substrate of the one or more substrates; and the energy source is supported by a second side of the substrate of the one or more substrates.
 28. The device according to claim 13, wherein: the organic light emitting diode contacts the energy source.
 29. The device according to claim 13, wherein: the energy source includes the first electrode of the organic light emitting diode.
 30. The device according to claim 29, wherein: the first electrode is an anode.
 31. A method for producing a light emitting device, comprising a substrate and an organic light emitting diode having an anode, an emitter layer and a cathode, wherein an energy source is integrated into the light emitting device to provide a voltage to the organic light emitting diode, comprising: providing one or more substrates; forming an energy source on the one or more substrates; forming an organic light emitting diode on the one or more substrates; encapsulating the energy source.
 32. The method of claim 31, wherein: forming the energy source includes forming a solar cell.
 33. The method of claim 31, wherein: encapsulating the energy source includes encapsulating the organic light emitting diode.
 34. A method for producing a light emitting device, comprising a substrate and an organic light emitting diode having an anode, an emitter layer and a cathode, wherein an energy source is integrated into the light emitting device to provide a voltage to the organic light emitting diode, comprising: constructing an energy source on a substrate; encapsulating the energy source; constructing an organic light emitting diode on the encapsulated energy source to form a combined energy source and organic light emitting diode; and encapsulating the combined energy source and organic light emitting diode.
 35. The method of claim 34, wherein: constructing an energy source on a substrate includes constructing a solar cell.
 36. A method for producing a light emitting device, comprising a substrate and an organic light emitting diode having an anode, an emitter layer and a cathode, wherein an energy source is integrated into the light emitting device to provide a voltage to the organic light emitting diode, comprising: forming a first cathode on a substrate; forming a first photoactive layer on the first cathode; forming an anode on the first photoactive layer; forming a second photoactive layer on the anode; forming a second cathode on the second photoactive layer; and forming an encapsulation to encapsulate the first and second cathodes.
 37. The method of claim 36 wherein: the first photoactive layer forms a layer of an energy carrier; and the second photoactive layer forms a layer of an organic light emitting diode.
 38. The method of claim 36 wherein: the first photoactive layer forms a layer of an organic light emitting diode; and the second photoactive layer forms a layer of an energy carrier.
 39. A method of operating a light emitting device that comprises a light emitting diode having a first electrode, an emitter layer and a second electrode, wherein the emitter layer is between the first and second electrodes and at least one energy source is integrated into the organic light emitting device such that the first and second electrodes, emitter layer and energy source are encapsulated, the method comprising: supplying a voltage from the energy source to the organic light emitting diode; and applying the supplied voltage across the first electrode and the second electrode; and emitting light when the voltage is applied across the first and second electrodes.
 40. The method of claim 39, further comprising: detecting an environmental influence selected from the group consisting of radiation, heat, pressure and sound, wherein detecting the environmental influence initiates the step of supplying a voltage.
 41. The method of claim 39, wherein: emitting light includes emitting light through the energy source.
 42. An electronic paper, comprising: one or more substrates; an organic light emitting diode supported by the one or more substrates, wherein the organic light emitting diode comprises: a first electrode; an emitter layer disposed on the first electrode; and a second electrode disposed on the emitter layer; and an energy source to apply a voltage to the organic light emitting diode wherein the energy source is supported by the one or more substrates. 